Ethanol

Ethanol
A bottle of ethanol
Names
Pronunciation /ˈɛθənɒl/
Preferred IUPAC name
Ethanol
Other names
  • Absolute alcohol
  • Alcohol
  • Cologne spirit
  • Drinking alcohol
  • Ethylic alcohol
  • EtOH
  • Ethyl alcohol
  • Ethyl hydroxide
  • Ethylene hydrate
  • Ethylol
  • Grain alcohol
  • Hydroxyethane
  • Methylcarbinol
Identifiers
CAS Number
3D model (JSmol)
Beilstein Reference
1718733
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.000.526
Gmelin Reference
787
KEGG
PubChem CID
UNII
UN number UN 1170
InChI
  • InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3 Y
    Key: LFQSCWFLJHTTHZ-UHFFFAOYSA-N Y
  • InChI=1/C2H6O/c1-2-3/h3H,2H2,1H3
    Key: LFQSCWFLJHTTHZ-UHFFFAOYAB
SMILES
  • OCC
Properties
Chemical formula
C2H6O
Molar mass 46.069 g·mol−1
Appearance Colourless liquid
Odor wine-like, pungent
Density 0.78945 g/cm3 (at 20 °C)
Melting point −114.14 ± 0.03 °C (−173.45 ± 0.05 °F; 159.01 ± 0.03 K)
Boiling point 78.23 ± 0.09 °C (172.81 ± 0.16 °F; 351.38 ± 0.09 K)
Solubility in water
Miscible
log P −0.18
Vapor pressure 5.95 kPa (at 20 °C)
Acidity (pKa) 15.9 (H2O), 29.8 (DMSO)
Magnetic susceptibility (χ)
−33.60·10−6 cm3/mol
Refractive index (nD)
1.3611
Viscosity 1.2 mPa·s (at 20 °C), 1.074 mPa·s (at 25 °C)
Dipole moment
1.69 D
Hazards
GHS labelling:
Pictograms
Signal word
Danger
Hazard statements
H225, H319, H360D
Precautionary statements
P210, P233, P240, P241, P242, P305+P351+P338
NFPA 704 (fire diamond)
2
3
0
Flash point 14 °C (Absolute)
Lethal dose or concentration (LD, LC):
  • 7060 mg/kg (oral, rat)
  • 3450 mg/kg (mouse)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1000 ppm (1900 mg/m3)
REL (Recommended)
TWA 1000 ppm (1900 mg/m3)
IDLH (Immediate danger)
3300 ppm
Safety data sheet (SDS)
Related compounds
Related compounds
  • Ethane
  • Methanol
Supplementary data page
Ethanol (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula CH3CH2OH. It is an alcohol, with its formula also written as C2H5OH, C2H6O or EtOH, where Et is the pseudoelement symbol for ethyl. Ethanol is a volatile, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. As a psychoactive depressant, it is the active ingredient in alcoholic beverages, and the second most consumed drug globally behind caffeine.

Ethanol is naturally produced by the fermentation process of sugars by yeasts or via petrochemical processes such as ethylene hydration. Historically it was used as a general anesthetic, and has modern medical applications as an antiseptic, disinfectant, solvent for some medications, and antidote for methanol poisoning and ethylene glycol poisoning. It is used as a chemical solvent and in the synthesis of organic compounds, and as a fuel source for lamps, stoves, and internal combustion engines. Ethanol also can be dehydrated to make ethylene, an important chemical feedstock. As of 2023, world production of ethanol fuel was 112.0 gigalitres (2.96×1010 US gallons), coming mostly from the U.S. (51%) and Brazil (26%).

The term “ethanol,” originates from the ethyl group coined in 1834 and was officially adopted in 1892, while “alcohol”—now referring broadly to similar compounds—originally described a powdered cosmetic and only later came to mean ethanol specifically. Ethanol occurs naturally as a byproduct of yeast metabolism in environments like overripe fruit and palm blossoms, during plant germination under anaerobic conditions, in interstellar space, in human breath, and in rare cases, is produced internally due to auto-brewery syndrome.

Ethanol has been used since ancient times as an intoxicant. Production through fermentation and distillation evolved over centuries across various cultures. Chemical identification and synthetic production began by the 19th century.