Sodium fluoride

Sodium fluoride
Names
Pronunciation /ˌsdiəm ˈflʊərd/
IUPAC name
Sodium fluoride
Other names
Florocid
Identifiers
CAS Number
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.789
EC Number
  • 231-667-8
KEGG
PubChem CID
RTECS number
  • WB0350000
UNII
UN number 1690
InChI
  • InChI=1S/FH.Na/h1H;/q;+1/p-1 Y
    Key: PUZPDOWCWNUUKD-UHFFFAOYSA-M Y
  • InChI=1/FH.Na/h1H;/q;+1/p-1
    Key: PUZPDOWCWNUUKD-REWHXWOFAH
Properties
Chemical formula
NaF
Molar mass 41.988173 g/mol
Appearance White to greenish solid
Odor odorless
Density 2.558 g/cm3
Melting point 993 °C (1,819 °F; 1,266 K)
Boiling point 1,704 °C (3,099 °F; 1,977 K)
Solubility in water
36.4 g/L (0 °C);
40.4 g/L (20 °C);
50.5 g/L (100 °C)
Solubility slightly soluble in HF, ammonia
negligible in alcohol, acetone, SO2, dimethylformamide
Vapor pressure 1 mmHg @ 1077 °C
Acidity (pKa) 3,20 (weak base, see HF)
Magnetic susceptibility (χ)
−16.4·10−6 cm3/mol
Refractive index (nD)
1.3252
Structure
Crystal structure
Cubic
Lattice constant
a = 462 pm
Molecular shape
Octahedral
Thermochemistry
Heat capacity (C)
46.82 J/(mol K)
Std molar
entropy (S298)
51.3 J/(mol K)
Std enthalpy of
formation fH298)
−573.6 kJ/mol
Gibbs free energy (ΔfG)
−543.3 kJ/mol
Pharmacology
A01AA01 (WHO) A12CD01 (WHO),
V09IX06 (WHO) (18F)
Hazards
GHS labelling:
Pictograms
Signal word
Danger
Hazard statements
H301, H315, H319, H335
NFPA 704 (fire diamond)
3
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
52–130 mg/kg (oral in rats, mice, rabbits)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 2.5 mg/m3
REL (Recommended)
TWA 2.5 mg/m3
IDLH (Immediate danger)
250 mg/m3 (as F)
Safety data sheet (SDS)
Related compounds
Other anions
Sodium chloride
Sodium bromide
Sodium iodide
Sodium astatide
Other cations
Lithium fluoride
Potassium fluoride
Rubidium fluoride
Caesium fluoride
Francium fluoride
Related compounds
TASF reagent
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Sodium fluoride (NaF) is an inorganic compound with the formula NaF. It is a colorless or white solid that is readily soluble in water. It is used in trace amounts in the fluoridation of drinking water to prevent tooth decay, and in toothpastes and topical pharmaceuticals for the same purpose. In 2022, it was the 221st most commonly prescribed medication in the United States, with more than 1 million prescriptions. It is also used in metallurgy and in medical imaging.